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This study extends research previously reported from our laboratory [SAE 2009-01-0285] on diesel NOx control utilizing a new generation of Lean NOx Trap (LNT) plus in-situ Selective Catalytic Reduction (SCR) catalyst systems. Key findings from this work include 1) evidence for a “non-ammonia” reduction pathway over the SCR catalyst (in addition to the conventional ammonia pathway), 2) high NOx conversions utilizing LNT formulations with substantially lower platinum group metal (PGM) loadings than utilized in earlier systems, 3) ability of the downstream SCR catalyst to maintain high overall system NOx efficiency with aged LNTs, and 4) effectiveness of both Cu- and Fe-zeolite SCR formulations to enhance overall system NOx efficiency. FTP NOx conversion efficiencies in excess of 95% were obtained on two light-duty vehicle platforms with lab-aged catalyst systems, thus showing potential of the LNT+SCR approach for achieving the lowest U.S. emissions standards

Robust on-board diagnosis of emission catalyst performance requires the development of artificially damaged "threshold" catalysts that accurately mimic the performance of damaged catalysts in customer use. The threshold catalysts are used by emissions calibrators to determine fore-aft exhaust oxygen sensor responses that indicate catalyst failure. Rather than rely on traditional trial-and-error processes to generate threshold catalysts, we have used a DFSS (Design For Six-Sigma) approach that explores, at a research level, the relationship between oxygen storage capacity (OSC) of the catalyst (i.e., the fundamental property dictating the response of the aft oxygen sensor) and key process input variables: high-temperature exposure, phosphorus poisoning, and catalyst "recovery."

An advanced diesel aftertreatment system utilizing Selective Catalytic Reduction (SCR) with urea for lean nitrogen oxides (NOx) control was tested on a 2.7L V6 Land Rover vehicle to demonstrate the capability of achieving Tier 2 Bin 5 and lower emission standards for light-duty trucks. SCR washcoat was applied to a diesel particulate filter (DPF) to perform NOx and particulate reduction simultaneously. Advanced SCR systems employed both traditional SCR catalysts and SCR-coated filters (SCRF) to improve the NOx reduction efficiency. The engine-out NOx level was adjusted by modifying the EGR (Exhaust Gas Recirculation) calibration. Cold start NOx performance was improved by SCR warm-up strategy and urea over injection. This study showed the advanced SCR system could tolerate higher NH₃ storage in the SCR catalyst, resulting in overall higher NOx conversion on the FTP-75 test cycle.

In 1999, the first generation NOx sensor from NGK Spark Plug, Co., Ltd. was commercialized for use in gasoline LNT NOx after-treatment systems [ 1 ]. Since then, as emissions regulations and OBD requirements have become more stringent, the demand for a high-accuracy NOx sensor with fast light-off has increased, particularly for diesel after-treatment systems. To meet such market demands, NGK Spark Plug, Co., Ltd. has developed, in collaboration with Ford Motor Company, a second generation NOx sensor.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOX emissions. Engine coolant is used to cool EGR coolers. The presence of a cold surface in the cooler causes fouling due to particulate soot deposition, condensation of hydrocarbon, water and acid. Fouling experience results in cooler effectiveness loss and pressure drop. In this study, possible soot deposition mechanisms are discussed and their orders of magnitude are compared. Also, probable removal mechanisms of soot particles are studied by calculating the forces acting on a single particle attached to the wall or deposited layer. Our analysis shows that thermophoresis in the dominant mechanism for soot deposition in EGR coolers and high surface temperature and high kinetic energy of soot particles at the gas-deposit interface can be the critical factor in particles removal.

The effects of combining premixed, low temperature combustion (LTC) with biodiesel are relatively unknown to this point. This mode allows simultaneously low soot and NOx emissions by using high rates of EGR and increasing ignition delay. This paper compares engine performance and emissions of neat, soy-based methyl ester biodiesel (B100), B20, B50, pure ultra low sulfur diesel (ULSD) and a Swedish, low aromatic diesel in a multi-cylinder diesel engine operating in a late-injection premixed LTC mode. Using heat release analysis, the progression of LTC combustion was explored by comparing fuel mass fraction burned. B100 had a comparatively long ignition delay compared with Swedish diesel when measured by start of ignition (SOI) to 10% fuel mass fraction burned (CA10). Differences were not as apparent when measured by SOI to start of combustion (SOC) even though their cetane numbers are comparable.

An aftertreatment system involving a LNT followed by a SCR catalyst is proposed for treating the NOx emissions from a diesel engine. NH3 (or urea) is injected between the LNT and the SCR. The SCR is used exclusively below 400°C due to its high NOx activity at low temperatures and due to its ability to store and release NH3 below 400°C, which helps to minimize NH3 and NOx slip. Above 400°C, where the NH3 storage capacity of the SCR falls to low levels, the LNT is used to store the NOx. A potassium-based LNT is utilized due to its high temperature NOx storage capability. Periodically, hydrocarbons are oxidized on the LNT under net lean conditions to promote the thermal release of the NOx. NH3 is injected simultaneously to reduce the released NOx over the SCR. The majority of the hydrocarbons are oxidized on the front portion of the LNT, resulting in the rapid release of stored NOx from that portion of the LNT.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.

A single-cylinder OKP (optimized kinetic process) engine, which uses homogeneous-charge compression-ignition (HCCI) technology, was tested, following a previous study, to evaluate the combustion system robustness and to improve the engine performance near the boundaries of the HCCI operating regime at light loads, high loads and high speed. To evaluate the robustness of HCCI combustion control, gasoline fuels with different RON were used, and the engine was tested at different coolant temperatures. It was demonstrated that the proposed HCCI control approaches could control the OKP engine system to operate robustly using different fuels and at different coolant temperatures. The effects of fuel injection timing and residual gas fraction on HCCI combustion and emissions, especially CO emissions and combustion efficiency, were tested at light loads; and the mechanisms were analyzed.

Homogeneous-charge compression-ignition (HCCI) technology has high potential to significantly reduce fuel consumption and NOx emissions over PFI engines. Control of the HCCI combustion process over the full range of conventional PFI operating conditions, however, has been a challenge. This study describes an HCCI-SI dual-mode engine system proposal based on new approaches to optimize the engine performance. A 0.658L single-cylinder engine was built and tested using these concepts. The engine was operated in HCCI mode from idle to 5.5 bar NMEP and up to 4750 rpm. NSFC in HCCI mode was about 175 g/kWh over most of the operating range except at very low load or near the high load boundary. At a part load of 1500 rpm and an equivalent BMEP of 2.62 bar, net indicated fuel efficiency was 50% higher than PFI engines and 30% higher than a prototype SC-DISI engine.

The control of NOx emissions is the greatest technical challenge in meeting future emission regulations for diesel engines. In this work, a modal analysis was performed for developing an engine control strategy to take advantage of fuel properties to minimize engine-out NOx emissions. This work focused on the use of EGR to reduce NOx while counteracting anticipated PM increases by using oxygenated fuels. A DaimlerChrysler OM611 CIDI engine for light-duty vehicles was controlled with a SwRI Rapid Prototyping Electronic Control System. Engine mapping consisted of sweeping parameters of greatest NOx impact, starting with OEM injection timing (including pilot injection) and EGR. The engine control strategy consisted of increased EGR and simultaneous modulation of both main and pilot injection timing to minimize NOx and PM emission indexes with constraints based on the impact of the modulation on BSFC, Smoke, Boost and BSHC.

As part of the P2000 hydrogen fueled internal combustion engine (H2ICE) vehicle program, an engine dynamometer research project was conducted in order to systematically investigate the unique hydrogen related combustion characteristics cited in the literature. These characteristics include pre-ignition, NOx emissions formation and control, volumetric efficiency of gaseous fuel injection and related power density, thermal efficiency, and combustion control. To undertake this study, several dedicated, hydrogen-fueled spark ignition engines (compression ratios: 10, 12.5, 14.5 and 15.3:1) were designed and built. Engine dynamometer development testing was conducted at the Ford Research Laboratory and the University of California at Riverside. This engine dynamometer work also provided the mapping data and control strategy needed to develop the engine in the P2000 vehicle.

Presented in this paper is an on-line method for estimating the sulfation levels within a lean NOx trap (LNT). Sulfur poisoning plays a major role in the reduction of oxygen and NOx storage capacity in an LNT. Indicators of LNT degradation are LNT NOx absorption efficiency and capacity. The estimation of LNT oxygen and NOx storage capacity is an on-line method of monitoring LNT NOx absorption efficiency and capacity. The estimation provides information regarding the sulfation level of the LNT. This estimate may be used in conjunction with lean burn strategies to initiate an LNT sulfur purging mechanism and maintain maximum fuel economy. In addition, the estimation of LNT oxygen and NOx storage capacity may be used for on-board diagnostics, LNT NOx absorption efficiency estimation, NOx purge fuel estimation, and many other applications.

Controlled Auto-Ignition (CAI) combustion has been achieved in a production type 4-stroke multi-cylinder gasoline engine. The engine was based on a Ford 1.7L Zetec-SE 16V engine with a compression ratio of 10.3, using substantially standard components modified only in design dimensions to control the gas exchange process in order to significantly increase the trapped residuals. The engine was also equipped with Variable Cam Timing (VCT) on both the intake and exhaust camshafts. It was found that the largely increased trapped residuals alone were sufficient to achieve CAI in this engine and with VCT, a range of loads between 0.5 and 4 bar BMEP and engine speeds between 1000 and 3500 rpm were mapped for CAI fuel consumption and exhaust emissions. The measured CAI results were compared with those of Spark Ignition (SI) combustion in the same engine but with standard camshafts at the same speeds and loads.

A simulated diesel exhaust is treated with a nonthermal plasma discharge under steady state conditions. The plasma effluent is then passed through a sodium zeolite-Y (NaY) catalyst followed by a platinum oxidation catalyst. Detailed FTIR measurements of gas composition are taken before, between, and after the treatment stages. The plasma discharge causes oxidation of NO primarily to NO2, with methyl nitrate and nitric acid byproducts. At the same time, HC is partially oxidized, creating species such as formaldehyde, acetaldehyde, CO and other partial oxidation products. When this mixture passes over the NaY catalyst, part of the NOx is reduced to N2, with the remainder primarily in the form of NO. Methyl nitrate decomposes to form methanol and NOx, and nitric acid is consumed. There is little HC conversion on this catalyst. Small quantities of HCN and N2O are formed. When the mixture then passes over the platinum catalyst, further NOx conversion occurs.

The catalytic activity of selected materials (BaY and NaY zeolites, and γ-alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective for the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250°C with 200ppm NOx at the inlet and a VHSV=12,000 h-1. The hydrocarbon reductants, n-octane and 1-propyl alcohol, have also shown high thermal catalytic activity for NOx removal over BaY, NaY and γ-alumina.

We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.

The purpose of this paper is to make a preliminary assessment of the potential toxicity of compounds that might be emitted from diesel vehicles using urea/SCR technology. The use of urea as a reductant in the removal of NOx from the exhaust of diesel-powered vehicles has the potential to emit at least seven thermal decomposition products and unreacted urea from the tail-pipe. These compounds include: urea, ammonia, cyanate ion, biuret, cyanuric acid, ammelide, ammeline, and melamine. The toxicity data base for these compounds, in general, is poor. In addition, there have been few, if any, studies examining the inhalation route of exposure - the most likely route of exposure for people from vehicle exhaust. The measurement and identification of these compounds from the exhaust of urea/SCR- equipped vehicles is needed to prioritize the kinds of health effects studies required to understand the toxicity of these compounds.

Lean NOx traps are being extensively examined (Ref. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 and 12) because they can be efficiently used to reduce the NOx emissions from port fuel injected and direct fuel injected spark ignited gasoline engines. A lean NOx trap (LNT) stores NOx during lean A/F engine operation. However, its storage capacity is limited and the LNT must be regenerated periodically by subjecting the LNT to momentary rich A/F operation for several seconds. The regeneration process releases the NOx that is chemically bonded to the washcoat and subsequently reduces it to N2 and O2. Fuel that contains a non-zero amount of sulfur will contaminate an LNT by significantly reducing its NOx storage capacity. Therefore, except for the case of a zero level of sulfur in the fuel, the LNT must be desulfated on a periodic basis. The desulfation process requires that the temperature of the LNT be raised to a temperature of about 650°C for several minutes.

Advances in fuel control strategy, emission system architecture, and catalyst technology have led to dramatic decreases in exhaust emissions in recent years. To continue this trend, especially at high mileages, the impact of engine oil derived contaminants will need to be minimized. In this study, the deactivating effects of oil-derived contaminants on advanced catalyst technologies was assessed using an oxalic acid washing technique to remove phosphorus and other oil-derived contaminants from fleet-aged automotive three-way exhaust catalysts. Acid washing removed most of the phosphorus on the catalyst (chief poison associated with decomposition of the engine oil antiwear additive ZDDP) without significantly affecting other catalyst properties. Catalysts from eight high-mileage vehicles were analyzed, representing four vehicle families.